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In this Monday, Oct. 13, 1975, file photo, singer-songwriter Marvin Gaye, left, sits with United Nations Secretary-General Kurt Waldheim, right, and Shirley Temple Black, U.S. Ambassador to Ghana, at the United Nations. Gaye is donating proceeds from his Sunday performance "Salute to the U.N." to UNESCO for an African literacy campaign. Temple, who died at her home near San Francisco, Monday, Feb. 10, 2014, at 85, sang, danced, sobbed and grinned her way into the hearts of Depression-era moviegoers and remains the ultimate child star decades later. (AP Photo/File)

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U.N. mediator for Syria Lakhdar Brahimi informs to media after the second day of the 2nd round of negotiation between the Syrian government and the opposition, during a press conference at the European headquarters of the United Nations, in Geneva, Switzerland, Tuesday, Feb. 11, 2014. (AP Photo/Keystone,Salvatore Di Nolfi)